King Charles will be formally proclaimed monarch at a historic Accession Council on Saturday.
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Charles has automatically become King on the death of his mother, but an Accession Council is usually convened at St James's Palace in London within 24 hours of the death of a sovereign.
It will be later following the death of the Queen because the announcement of her death did not come until early evening on Thursday, meaning there was not enough time to set the plans in motion for Friday morning.
Historically, the entire Privy Council is summoned to the Accession Council to oversee the formal proclamation of a new monarch.
But with the number of privy counsellors - who are lifetime members and mostly past and present politicians - now standing at more than 700, restrictions have been put in place.
Just 200 will be summoned, and those cut will be asked to enter an annual ballot for a few remaining seats.
The Accession Council must take place before parliament meets, and parliament should meet as soon as practicable after the death of a sovereign.
The Accession Council is divided into two parts, and is presided over by the Lord President of the Council, Penny Morduant, who has ministerial responsibility for the Privy Council Office.
The chosen Privy counsellors - without the King - will gather at St James's Palace to proclaim the new sovereign, joined by Great Officers of State, the Lord Mayor and City Civic party, Realm High Commissioners and some senior civil servants.
Camilla - the new Queen - and the Duke of Cornwall and Cambridge are already privy counsellors so will be present.
When the meeting begins, the Lord President announces the death of the sovereign and calls upon the Clerk of the Council to read aloud the text of the Accession Proclamation.
It will include Charles's chosen title as King - already known to be King Charles III.
The platform party - made up of Camilla and William, the Archbishop of Canterbury, the Lord Chancellor, the Archbishop of York, the Prime Minister, the Lord Privy Seal, the Lord Great Chamberlain, the Earl Marshal and the Lord President - sign the Proclamation.
The Lord President then calls for silence and reads the remaining items of business, which deal with the dissemination of the Proclamation and various orders giving directions for firing guns at Hyde Park and the Tower of London.
Charles then enters and holds his first Council, which is only attended by Privy Counsellors.
He will first make a personal declaration about the death of the Queen.
Then one of his next acts will be to take the oath to preserve the Church of Scotland - because in Scotland there is a division of powers between Church and State.
He will read it out loud and sign two identical Instruments recording the taking of the oath, with his signature witnessed by Camilla and William, and others including the Secretary of State for Scotland and the Scottish First Minister.
Other business will be dealt with, including the use of the Seals, to "facilitate the continuity of government".
Privy counsellors will sign the Proclamation as they leave.
After the Accession Council, the first public proclamation of the new sovereign is read in the open air from the Friary Court balcony by the Garter King of Arms at St James's Palace.
Amid great ceremony, trumpeters usually play a fanfare from the balcony and gun salutes are fired in Hyde Park and at the Tower of London at the same time.
The Proclamation will then be read at the Royal Exchange in the City of London and in other cities including Edinburgh, Cardiff and Belfast and usually at Windsor and in York.
The Privy Council dates from the time of the Norman kings when the monarch met in private - hence the description Privy - with a group of trusted counsellors who fulfilled the role the cabinet performs today.
Australian Associated Press
